Transition metal complexes, possessing redox-isomerism as a basis for new smart sensing materials |
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| Alla V. Arapova, Michail P. Bubnov, Nina A. Skorodumova, Natalia N. Smirnova, Gleb A. Abakumov |
- Abstract:
- Extensive studies on bistable molecules which can transform their physical properties with external stimuli, for developing molecule-based sensors have been performed [1-3]. It is known that some semiquinonato transition metal complexes undergo a redox-isomeric (valence-tautomeric) interconversion induced by temperature, light, pressure and magnetic field. This paper presents results of thermodynamic studies of some complexes which exhibit redoxisomerism.
- Keywords:
- redox-isomerism, o-semiquinonic complexes of cobalt, thermodynamic properties
- Download:
- IMEKO-TC4-2014-421.pdf
- DOI:
- -
- Event details
- IMEKO TC:
- TC4
- Event name:
- TC4 Symposium 2014
- Title:
20th IMEKO TC4 Symposium on Measurements of Electrical Quantities (together with 18th TC4 International Workshop on ADC and DCA Modeling and Testing, IWADC)
"Research on Electrical and Electronic Measurement for the Economic Upturn"- Place:
- Benevento, ITALY
- Time:
- 15 September 2014 - 17 September 2014